Using a fork, prick pork chops all over and add to a bag or shallow dish (13x9).
Whisk to combine chopped habanero, lemongrass, garlic, orange juice, fish sauce, coconut aminos and vinegar in a small bowl. Pour marinade over pierced pork chops and seal in bag or shallow dish and turn to coat. Let marinate at room temperature, turning occasionally, for 30 minutes.
Prepare grill to medium-high heat; oil grate with olive oil. Remove pork chops from marinade and pat dry. Season with salt and pepper. Grill four minutes over direct heat, until charred and flip, cooking for 3-4 more minutes, until cooked through, about 6–8 minutes total. Transfer to a platter and let rest 5 minutes before cutting.